Preparation and Characterization of Pyridin-2-amine Functionalized Thiadiazole-Embedded Polymer Inclusion Membrane and Utilization of Its Heavy Metal Transport Efficiency

Cicek M., Cay S., Engin M. S., Sener N., Aldwib A. E. O., Gur M.

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, vol.94, no.8, pp.2038-2043, 2024 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 94 Issue: 8
  • Publication Date: 2024
  • Doi Number: 10.1134/s1070363224080176
  • Journal Name: RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core
  • Page Numbers: pp.2038-2043
  • Kocaeli University Affiliated: Yes

Abstract

3-[5-(Cycloheximino)-4,5-dihydro-1,3,4-thiadiazol-2-yl]pyridine-2-amine was synthesized and used to make a novel pyrazole derivative embedded polymer inclusion membrane (Py@PIM). The surface and structure morphology of Py@PIM was detected using thermogravimetric analysis, FT-IR spectroscopy and scanning electron microscopy. Donnan dialysis system was also used to assess the transport efficacy of Py@PIM towards 5 heavy metals (Co, Cd, Cu, Ni, Pb). The results show that according to the kinetic coefficient, the order is Pb > Ni > Co > Cd > Cu. Similar kinetic order was also observed in multiple cation experiments, in experiments where all cations were mixed in a single cell.