A convenient synthesis of 3,4-disubstituted-1,2,4-thiadiazole-5(4H)-thiones

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Atıf İçin Kopyala

Agirbas H., Kahraman K.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.134, ss.381-389, 1998 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 134
• Basım Tarihi: 1998
• Doi Numarası: 10.1080/10426509808545478
• Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier
• Sayfa Sayıları: ss.381-389
• Kocaeli Üniversitesi Adresli: Hayır

Özet

3,4-Disubstituted-1,2,4-oxadiazole-5(4H)-ones were obtained from the reaction of substituted amide oximes with ethylchloroformate. These compounds were treated with P2S5 to give corresponding 1,2,4-oxadiazole-5-thiones. Rearrangement of 1,2,4-oxadiazole-5-thiones, catalysed by metallic copper, yielded 1,2,4-thiadiazole-5-ones. The reaction of 1,2,4-thiadiazole-5-ones with P2S5 gave 1,2,4-thiadiazole-5-thiones.