STEREOCHEMISTRY OF THE TETRACYANOETHYLENE-CATALYZED METHANOLYSIS OF STEROIDAL EPOXIDES


Uyanık C.

Journal Of Chemical Research-S, sa.8, ss.334-335, 1995 (SCI Expanded İndekslerine Giren Dergi)

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 1995
  • Doi Numarası: 10.1002/chin.199549234
  • Dergi Adı: Journal Of Chemical Research-S
  • Sayfa Sayıları: ss.334-335

Özet

In contrast to simpler systems, the methanolysis of the epimeric C-4 and C-5 steroidal epoxides catalysed by tetracyanoethylene is shown to have a regiochemistry dominated by the trans periplanar relationship between the resultant alkoxy and hydroxy groups.