Steric effects in the tetracyanoethylene catalysed methanolysis of some cyclohexane epoxides

Uyanik, CAVİT; Hanson, JR; Hitchcock, PB; Lazar, MA

doi:10.1016/j.tet.2005.01.030

Steric effects in the tetracyanoethylene catalysed methanolysis of some cyclohexane epoxides

Atıf İçin Kopyala

Uyanik C. , Hanson J., Hitchcock P., Lazar M.

TETRAHEDRON, cilt.61, sa.17, ss.4323-4327, 2005 (SCI İndekslerine Giren Dergi)

Cilt numarası: 61 Konu: 17
Basım Tarihi: 2005
Doi Numarası: 10.1016/j.tet.2005.01.030
Dergi Adı: TETRAHEDRON
Sayfa Sayıları: ss.4323-4327

Özet

The presence of a hydroxyl group has been shown to direct the regiochemistry and stereochemistry of the TCNE methanolysis of cyclohexane hydroxy-epoxides. alpha-Pinene epoxide underwent cleavage to form the 8-methyl ether of trans-sobrerol. (c) 2005 Elsevier Ltd. All rights reserved.