Polymerization of 3-glycidyloxypropyltrimethoxysilane with different catalysts

Kayan A.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.123, sa.6, ss.3527-3534, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 123 Sayı: 6
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1002/app.34859
  • Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3527-3534
  • Anahtar Kelimeler: NMR, polymer synthesis and characterization, ring-opening polymerization, RING-OPENING POLYMERIZATION, PROPYLENE-OXIDE, STRUCTURAL-CHARACTERIZATION, POLY(PROPYLENE OXIDE), LEWIS-ACID, CONDENSATION, HYDROLYSIS, PRECURSORS, POLYMERS, EPOXIDE
  • Kocaeli Üniversitesi Adresli: Evet

Özet

Polymerization reactions of 3-glycidyloxypropyltrimethoxysilane (GPTS) were carried out by different catalysts, potassium hydroxide, potassium tert-butoxide, and tetraphenylporphyrin aluminum chloride (TPPAlCl), and tetrafluorophthalate zironium isopropoxide complex. Polymer samples obtained from the ring-opening polymerization of GPTS were characterized by Fourier transform infrared spectroscopy, NMR spectroscopy, electrospray ionization mass spectroscopy, and gel permeation chromatography. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 123: 3527-3534, 2012