Synthesis and characterization of novel supercryptands-fused porphyrazines


BİLGİN A., ERTEM B.

INORGANIC CHEMISTRY COMMUNICATIONS, vol.11, no.10, pp.1113-1116, 2008 (SCI-Expanded) identifier identifier

Abstract

Novel metal-free (8, 9), magnesium and zinc porphyrazines (6, 7, 10, 11) containing four peripheral tetraza-dithiahexaoxa cyclindrical or spherical cryptand units have been prepared by tricyclotetramerization reactions using supercryptand 4 or S. All new products have been characterized by a combination of mass, elemental analyses, electronic absorption, Fr-IR, (1)H and (13)C NMR spectroscopy. (C) 2008 Elsevier B.V. All rights reserved.