Synthesis and characterization of Zr, Ti, Al-phthalate and pyridine-2-carboxylate compounds and their use in ring opening polymerization

Yalcin G., KAYAN A.

APPLIED CATALYSIS A-GENERAL, cilt.433, ss.223-228, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 433
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1016/j.apcata.2012.05.019
  • Dergi Adı: APPLIED CATALYSIS A-GENERAL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.223-228
  • Anahtar Kelimeler: Metal alkoxides, Phthalate catalysts, Ring-opening, Pyridine-2-carboxylate catalysts, STRUCTURAL-CHARACTERIZATION, ADDITION-REACTIONS, COMPLEXES, ALKOXIDES, ACID, ESTERS
  • Kocaeli Üniversitesi Adresli: Evet

Özet

Zirconium, titanium and aluminum phthalate (PH, C8H4O4) and pyridine-2-carboxylate (Pyca, C6H4NO2) compounds were prepared by reaction of Zr, Ti and Al-alkoxides with phthalic acid (PHA) and pyridine-2-carboxylic acid (PycaH) in alcohol. All new complexes were characterized by a combination of elemental analysis, NMR and FTIR spectroscopy and used in polymerization of 3-glycidyloxypropyltrimethoxysilane (GPTS) in order to see their catalytic activity over epoxides. Especially, Al, Ti and Zr-phthalate catalysts were more effective in ring opening of GPTS when compared to Al, Ti and Zr-pyridine-2-carboxylate catalysts. Poly-GPTS were characterized by H-1, C-13 NMR and gel permeation chromatography (GPC). (C) 2012 Elsevier B.V. All rights reserved.