Did ore diversity reflect selection beyond colour? a multi-analytical insight into early copper ore procurement at Gre Fılla


MUŞKARA Ü., TELLİ M. B., Bozbaş S. K., KONAK A.

ARCHAEOLOGICAL AND ANTHROPOLOGICAL SCIENCES, cilt.17, sa.12, 2025 (SCI-Expanded, AHCI, SSCI, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 17 Sayı: 12
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1007/s12520-025-02348-7
  • Dergi Adı: ARCHAEOLOGICAL AND ANTHROPOLOGICAL SCIENCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Arts and Humanities Citation Index (AHCI), Social Sciences Citation Index (SSCI), Scopus, IBZ Online
  • Anahtar Kelimeler: Alteration, Colour, Copper ore, Patina, PPNB, pXRF
  • Kocaeli Üniversitesi Adresli: Evet

Özet

This study investigates copper ores from the Pre-Pottery Neolithic (PPN) site of Gre F & imath;lla, Turkey, employing a multi-analytical approach to understand the challenges in characterizing altered archaeological materials. The chemical and mineralogical properties of seven copper ore fragments and the effects of burial alteration were examined using X-ray diffraction (XRD), scanning electron microscopy with energy dispersive X-ray spectroscopy SEM-EDS, handheld portable X-ray fluorescence spectrometry (pXRF), and flame atomic absorption spectrometry (FAAS) to reconstruct their original composition. Results revealed a diverse assemblage of copper minerals, including copper oxides, sulphides, and mixed phases. Element maps visualized the distribution of Cu, Si, Ca, Al, and O, and SEM imaging revealed the micro-structural features of the matrix, including evidence of malachite dissolution and secondary patina formation. The patina of the samples is characterized by elevated Cu content, with XRD identifying malachite (Cu2CO3(OH)(2)), quartz (SiO2), calcite (CaCO3), and magnetite (Fe3O4) among secondary phases. The diversity of copper minerals identified suggests that the inhabitants recognized and engaged with materials of different properties.