<i>In</i><i> situ</i> polyaniline polymerization on electrospun cellulose acetate nanofibers derived from recycled waste filter butts of cigarettes for the enhanced removal of methyl orange and rhodamine
CHEMICAL ENGINEERING RESEARCH & DESIGN, cilt.201, ss.18-30, 2024 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 201
- Basım Tarihi: 2024
- Doi Numarası: 10.1016/j.cherd.2023.11.043
- Dergi Adı: CHEMICAL ENGINEERING RESEARCH & DESIGN
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, Environment Index, Food Science & Technology Abstracts, Greenfile, INSPEC, Metadex, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
- Sayfa Sayıları: ss.18-30
- Kocaeli Üniversitesi Adresli: Hayır
Özet
In this study, waste cigarette butts (CBs) were processed to produce electrospun cellulose acetate (CA) nanofibrous membranes modified with polyaniline (PANI) via chemical oxidation polymerization. This cost-effective method of preparing CA coated with PANI was initially investigated by comparing CA, CA-PANI, and CA-dPANI (as deprotonated PANI) for the rapid adsorption of cationic and anionic dyes. The results depicted CA-PANI with the highest dye removal capacity. As the optimum material, CA-PANI was applied to remove methyl orange (MO) and rhodamine chloride (RC) dye from an aqueous phase. Essential factors: contact time, solution pH, initial dye concentration, nanofiber dosage, and temperature of solution were evaluated with maximum equilibrium adsorption capacity and removal percentage achieved for MO as 24.87 mg/g and 99 %, for RC as 6.93 mg/g and 55 %, respectively. The adsorptive experimental data for both dyes best fitted the pseudo -second -order kinetic, intraparticle diffusion, and Freundlich models. Moreover, the thermodynamics result indicated the adsorption processes were exothermic and spontaneous in nature. Reusability studies also showed the stable performance of CA-PANI material for up to 7 adsorption -desorption cycles. The high dye removal efficiency suggests that the adsorbent material in the water filtration of azo dyes.