The stereochemistry of the Grignard reaction of some boat ring ketones in the diterpenoids


Uyanik C., Hanson J., Hitchcock P.

JOURNAL OF CHEMICAL RESEARCH-S, ss.530-532, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: Konu: 8
  • Basım Tarihi: 2004
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
  • Sayfa Sayısı: ss.530-532

Özet

The stereochemistry of the addition of methylmagnesium bromide to boat ring B C-6 and C-7 ketones of the rosane and to C-16 of the beyerane diterpenoids has been shown to take place from the less-hindered face of the molecule.