The stereochemistry of the Grignard reaction of some boat ring ketones in the diterpenoids

Uyanik C., Hanson J., Hitchcock P.

JOURNAL OF CHEMICAL RESEARCH, sa.8, ss.530-532, 2004 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Sayı: 8
  • Basım Tarihi: 2004
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.530-532
  • Kocaeli Üniversitesi Adresli: Evet

Özet

The stereochemistry of the addition of methylmagnesium bromide to boat ring B C-6 and C-7 ketones of the rosane and to C-16 of the beyerane diterpenoids has been shown to take place from the less-hindered face of the molecule.