The stereochemistry of the Grignard reaction of some boat ring ketones in the diterpenoids

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Atıf İçin Kopyala

Uyanik C., Hanson J., Hitchcock P.

JOURNAL OF CHEMICAL RESEARCH-S, ss.530-532, 2004 (SCI İndekslerine Giren Dergi)

• Cilt numarası: Konu: 8
• Basım Tarihi: 2004
• Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
• Sayfa Sayısı: ss.530-532

Özet

The stereochemistry of the addition of methylmagnesium bromide to boat ring B C-6 and C-7 ketones of the rosane and to C-16 of the beyerane diterpenoids has been shown to take place from the less-hindered face of the molecule.