The stereochemistry of the Grignard reaction of some boat ring ketones in the diterpenoids

Uyanik C., Hanson J., Hitchcock P.

JOURNAL OF CHEMICAL RESEARCH, no.8, pp.530-532, 2004 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: Issue: 8
  • Publication Date: 2004
  • Journal Name: JOURNAL OF CHEMICAL RESEARCH
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.530-532
  • Kocaeli University Affiliated: Yes

Abstract

The stereochemistry of the addition of methylmagnesium bromide to boat ring B C-6 and C-7 ketones of the rosane and to C-16 of the beyerane diterpenoids has been shown to take place from the less-hindered face of the molecule.