The stereochemistry of epoxidation of 5β-methyl-19-norsteroidal 9,10-alkenes

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UYANIK C., Malay A., Hanson J. R., Hitchcock P. B., Yildirim K.

Journal of Chemical Research, sa.4, ss.236-237, 2005 (SCI-Expanded, Scopus)

• Yayın Türü: Makale / Tam Makale
• Basım Tarihi: 2005
• Doi Numarası: 10.3184/0308234054213519
• Dergi Adı: Journal of Chemical Research
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.236-237
• Anahtar Kelimeler: Chromium trioxide, Epoxidation, Oxidations, Steroidal 9(10)-alkenes, Westphalen rearrangement
• Kocaeli Üniversitesi Adresli: Evet

Özet

Crystallographic studies have shown that the oxidation of 3β,6β-dihydroxy-5β-methyl-19-norsteroidal 9(10)-alkenes with chromium trioxide leads to 9α,10α-epoxides as minor products.