Some rearrangements of gibberellins catalysed by tetracyanoethylene


Hanson J., UYANIK C.

JOURNAL OF CHEMICAL RESEARCH-S, no.11, pp.676-678, 1998 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: Issue: 11
  • Publication Date: 1998
  • Doi Number: 10.1039/a804144j
  • Journal Name: JOURNAL OF CHEMICAL RESEARCH-S
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.676-678
  • Kocaeli University Affiliated: Yes

Abstract

Tetracyanoethylene in methanol has been shown to catalyse the rearrangement of ring a of gibberellic acid to the 3 beta-methyl ether of gibberellenic acid and to the 19-2 alpha-isolactone whilst the 13-hydroxygibberellin 16,17-epoxides are converted to 8:13-isogibberellins.