Second International Conference on Bioactive, Organic and Inorganic Advanced Materials and Clean Technologies, Sofija, Bulgaristan, 27 - 29 Nisan 2026, ss.93, (Özet Bildiri)
High-entropy alloys have become a widely studied
category of advanced materials due to the increased mixing entropy and phase
stability provided by multi-component alloy design [1]. The controllability of
their microstructural components allows precise regulation of mechanical,
thermal, and electrochemical properties [2]; such a capability inevitably makes
the chemical composition and phase constitution decisive factors in designing
many material-specific structural properties. [3]. In this study, equimolar
AlCoCrFeNi and AlCoCrFeNi1.5 alloys were produced by spark plasma
sintering (SPS) and systematically examined in terms of microstructure and
corrosion performance. As shown in Figure 1, XRD patterns confirmed the
presence of BCC + FCC solid solution structures, while SEM/EDS analyses
revealed distinct microstructural differences, with AlCoCrFeNi1.5
exhibiting a higher fraction of the FCC phase. Electrochemical tests in 3.5
wt.% NaCl demonstrated that AlCoCrFeNi1.5 possesses superior
corrosion resistance, attributed to a more stable, chromium-enriched passive
film. These results clearly establish the structure–property relationship and
highlight the corrosion advantages of FCC-rich AlCoCrFeNi1.5 alloys
produced by SPS.