Structural phase transitions in AgTa0.5Nb0.5O3 thin films

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Han Y., Reaney I. M. , Johnson-Wilke R. L. , Telli M. B. , Tinberg D. S. , Levin I., ...Daha Fazla

JOURNAL OF APPLIED PHYSICS, cilt.107, 2010 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 107 Konu: 12
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1063/1.3447753


Octahedral tilt transitions in epitaxial AgTa0.5Nb0.5O3 (ATN) films grown on (001)(p) (where p =pseudocubic) oriented SrRuO3/LaAlO3 and LaAlO3 substrates were characterized by electron diffraction and high resolution x-ray diffraction. It was found that the ATN films exhibited octahedral rotations characteristic of the Pbcm space group, similar to those seen in bulk materials; however, the temperature of the M-3 <-> M-2 phase transition has been suppressed by similar to 250 K due to the fact that the correlation length for rotations about c(p) was significantly reduced. The average off-center B-cation displacements, which signify the degree of long-range order for these local cation positions, were negligibly small compared to bulk materials, as inferred from the near-zero intensity of the 1/4(00l)(p)-type reflections. On cooling, pronounced ordering of B-cation displacements occurred at approximate to 60 K which is significantly lower compared to bulk (approximate to 310 K). The onset of this ordering coincides with a broad maximum in relative permittivity as a function of temperature. It is believed that point and planar defects in thin ATN films disrupt the complex sequence of in-phase and antiphase rotations around c(p) thereby reducing the effective strength of interactions between the tilting and cation displacements. (C) 2010 American Institute of Physics. [doi:10.1063/1.3447753]