Synthesis and theoretical study of 5-methoxyisatin-3-(N-cyclohexyl)thiosemicarbazone and its Ni(II) and Zn(II) complexes


Kandemirli F., ARSLAN T., Karadayi N., Ebenso E. E. , Koksoy B.

JOURNAL OF MOLECULAR STRUCTURE, cilt.938, ss.89-96, 2009 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 938
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1016/j.molstruc.2009.09.009
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Sayfa Sayıları: ss.89-96

Özet

5-Methoxyisatin-3-(N-cyclohexyl)thiosemicarbazone (H2MICT) and its Zn(II) and Ni(II) complexes have been synthesized and characterized using IR, H-1 NMR, C-13-NMR, MS, UV and elemental analysis. (H2MICT) ligand has been characterized with X-ray diffraction method also The possible structures and IR data of the studied molecules were Calculated and compared with experimental results using B3LYP/6-31G(d,p) and B3LYP/LANL2DZ methods. (C) 2009 Elsevier B.V. All rights reserved.