The stereochemistry of an elimination reaction accompanying the hydroboration of a steroidal allylic alcohol

Hanson J., Liman M., UYANIK C.

JOURNAL OF CHEMICAL RESEARCH-S, sa.3, ss.126-127, 1998 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Sayı: 3
  • Basım Tarihi: 1998
  • Doi Numarası: 10.1039/a708181b
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.126-127
  • Kocaeli Üniversitesi Adresli: Evet

Özet

Deuterium labelling studies have shown that the facile elimination of the 5 beta-hydroxy group observed in the course of hydroboration of a 5 beta-hydroxyandrost-3-ene may involve a trans diaxial borane-borinate elimination coupled with a syn transfer of hydrogen from the borinate.