Electrochemical water softening: bridging laboratory advances and industrial implementation for energy-efficient water hardness control


Seidu I., ATALAY GENGEÇ N., Bajpai M., GENGEÇ E., Kobya M.

Separation and Purification Technology, cilt.396, 2026 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Derleme
  • Cilt numarası: 396
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1016/j.seppur.2026.138032
  • Dergi Adı: Separation and Purification Technology
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Anahtar Kelimeler: Electrocoagulation, Electrode materials, Electroprecipitation, Fouling and Passivation, Techno-Economic viability, Water softening
  • Kocaeli Üniversitesi Adresli: Evet

Özet

This review critically synthesizes recent advances in electrochemical water softening (EWS), with emphasis on electrode materials, reactor geometries, operational optimization, and scale-up feasibility. It compares capacitive deionization (CDI), electrodialysis (ED), and electrochemical precipitation (ECP) approaches, including electrocoagulation and electroprecipitation, highlighting typical performance ranges such as hardness removal efficiencies (>80-95%), specific energy consumption (∼0.5-3.5 kWh.m-3), and water recovery (>70-90%) depending on water composition and process configuration. Special attention is given to electroprecipitation, with comprehensive discussions on electrode properties, fouling and degradation mechanisms, and control strategies, supported by multi-technique characterization of electro-precipitates. The review further integrates techno-economic and environmental assessments, including valorization pathways for precipitates and cost-benefit considerations for industrial deployment. By synthesizing laboratory findings with reactor-scale performance and long-term viability, this work provides a comprehensive framework that bridges existing knowledge gaps and guides the sustainable application of electrochemical softening technologies.