The stereochemistry of the 1,2-addition of Grignard reagents to some steroidal unsaturated ketones

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Atıf İçin Kopyala

Uyanik C., Hanson J., Hitchcock P.

JOURNAL OF CHEMICAL RESEARCH, ss.474-476, 2003 (SCI İndekslerine Giren Dergi)

• Cilt numarası: Konu: 8
• Basım Tarihi: 2003
• Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
• Sayfa Sayıları: ss.474-476

Özet

The stereochemistry of 3beta,17beta-dihydroxy-3alpha-ethylandrost-4-ene, 3alpha,17beta-dihydroxy-3beta-methylestr-4-ene and 3beta-acetoxy-7alpha,17beta-dihydroxy-7beta-methylandrost-5-ene, which were obtained by Grignard reactions from the corresponding alphabeta-unsaturated ketones, have been established by X-ray crystallography.