Copper-catalysed rearrangement of 4-substituted-2,3-1H-benzoxazine-1-thiones


Agirbas H., Guner S.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.161, ss.257-263, 2000 (SCI-Expanded) identifier identifier

Özet

4-Substituted-2,3-1H-benzoxazine-1-thiones were prepared by the treatment of the corresponding benzoxazine-1-ones with P2S5. The thermal rearrangement of 4-substituted-2,3-1H-benzoxazine-1-thiones, catalysed by metallic copper, yielded 4-substituted-2,3-1H-benzthiazine-1-ones.