Comparison of Acid and Alkaline Pretreatment Methods for the Bioethanol Production from Kitchen Waste


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Kerimak Öner M. N.

Green Energy and Technology, The Role of Exergy in Energy and the Environment, S. Nižetić,A. Papadopoulos, Editör, Springer Nature, Split, ss.363-372, 2018

  • Yayın Türü: Kitapta Bölüm / Araştırma Kitabı
  • Basım Tarihi: 2018
  • Yayınevi: Springer Nature
  • Basıldığı Şehir: Split
  • Sayfa Sayıları: ss.363-372
  • Editörler: S. Nižetić,A. Papadopoulos, Editör
  • Kocaeli Üniversitesi Adresli: Evet

Özet

The use of abundant waste materials with high carbohydrate content may contribute substantially to reduction of biofuels production costs. The kitchen waste fraction in municipal solid waste contains high organic matter particulary carbohydrate that can be contributed to fermentable sugar production for subsequent conversion to bioethanol. This research reviews pretreatment techniques to enhance digestion of kitchen waste, including mechanical, thermal, chemical and biological methods for bioethanol production. The present studies aimed at optimizing the effect of different pretreatment methods are discussed independently and its combination for maximizing the production of fermentable soluble sugars. To this end, acid pretreatment of kitchen waste samples was performed with sulphuric acid (0-5% H2SO4) and hydrochloric acid (0-5% HCl) at 30-100°C for 0-120 min treatment time. Alternatively, alkaline pretreatment was performed with sodium hydroxide solution (0-5% NaOH) at 30-120°C for 0-120 min treatment time. Both acid and alkaline pretreatments were combined with enzymatic hydrolysis (170mg protein/kg wet waste) at constant pH, temperature and time (pH:4.8, 50°C and 6h respectively). The effectiveness of each pretreatmant method was compared based on percentage of glucose recovery. Changes in structure of kitchen waste was also observed microscopically (SEM) and spectroscopically (FTIR) leading to enhance the digestibility of kitchen waste with different liquefaction methods and its combination.