LEVELS and SOURCE DIAGNOSTICS OF PAHs IN STREET DUST COLLECTED FROM DIFFERENT LOCATIONS OF HIGHWAYS in KOCAEL


Civan M.

15TH INTERNATIONAL ISTANBUL SCIENTIFIC RESEARCH CONGRESSES ON LIFE, SOCIAL, AND HEALTH SCIENCES, İstanbul, Türkiye, 9 - 11 Aralık 2023, cilt.1, ss.1-14

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Cilt numarası: 1
  • Basıldığı Şehir: İstanbul
  • Basıldığı Ülke: Türkiye
  • Sayfa Sayıları: ss.1-14
  • Kocaeli Üniversitesi Adresli: Evet

Özet

Polycyclic aromatic hydrocarbons (PAHs) resulting from incomplete combustion of organic materials are ubiquitous environmental pollutants. Due to their carcinogenic, mutagenic, and toxic effects, effective mitigation strategies for these pollutants are needed, especially in urban areas. Therefore, the number of studies focused on the detection of PAH in several media has increased in recent years. Street dust is a good indicator of the quality of the urban air environment. Because of their large surface areas, dust is a sink for several pollutants. On the other hand, humans are continuously exposed to this contaminated dust because of its re-suspension into air. In the current study, six street dust samples were collected from different parts of the highways along Kocaeli. The total 16 PAH (Σ16PAHs) concentrations ranged from 221.25 ng/g to 2856.86 ng/g with a mean value of 1070 ng/g. The most abundant congeners in the dust samples were pyrene with a mean concentration of 256.31 ng/g (55.22-900.17 ng/g), followed by phenanthrene (mean: 143.27 ng/g , range: 38.93–432.21 ng/g) and benzo[k]fluoranthene (mean: 137.49 ng/g , range: 1.37–728.94 ng/g). These three top congeners contributed to approximately half of the total PAH concentrations in the dust samples.

 

Although Tavsanlı has the highest annual average of the daily vehicles passing among samples, Σ16PAHs in the dust from Dilovası-D100 were detected at the highest level (2857 ng/g). High molecular weight (HMW)–PAHs significantly contributed to total PAH (ranged from 68.33% to 89,69%) while Low Molecular Weight (LMW)-PAHs were from 10.31% to 28.19%.  PAH diagnostic ratios were also calculated to identify potential sources of PAHs in the samples.  The results indicated that the main sources of PAHs in street dust were vehicle emissions, especially those with diesel engines. Industrial emissions should be considered in the samples from Tavsanlı D100 and Dilovası D-100. Applying mitigation strategies such as enforcing stringent vehicle emission standards and encouraging the use of cleaner fuels and technologies  would be useful to reduce PAH levels in Kocaeli, a city with high traffic loads