Complexation of titanium alkoxides with pentenoic acid and allylacetoacetate and their hydrolysis and addition reactions with H-silanes


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Kayan A. , Hoebbel D., Schmidt H.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.95, ss.790-796, 2005 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 95 Konu: 4
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1002/app.21315
  • Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
  • Sayfa Sayıları: ss.790-796

Özet

Complexation reactions of titanium tetraethoxide [Ti(OEt)(4)] and titanium tetra-n-butoxide [Ti(OBu")(4)] with 3-pentenoic acid (PA) and allylacetoacetate (AAA), in a 1 : 1M ratio, were studied in ethanol solution at room temperature. C-13-NMR and FTIR spectra showed that all PA and AAA completely reacted with both titanium alkoxides. Hydriclosilane compounds such as triethoxysilane and triethylsilane were added to titanium chelate complexes in a 1 : 1M ratio. The investigation of products by C-13- and (SiNMR)-Si-29 and FTIR showed additions of -SiH to the C=C double bond. The hydrolysis of titanium-PA and AAA complexes, by water in 1 : 4 ratios, resulted in released PA in an amount of 10% and AAA of 20%. The stability of hydrolyzed products was investigated by C-13-NMR, "SiNMR, and FTIR. (C) 2004 Wiley Periodicals, Inc.