Synthesis and characterization of a new (E, E)-dioxime and its homo and heteronuclear complexes containing macrobicylic moieties


Mendil D., Bilgin A. , Gok Y., Senturk H.

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, cilt.43, ss.265-270, 2002 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 43
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1023/a:1021279728967
  • Dergi Adı: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Sayfa Sayıları: ss.265-270

Özet

A new N,N'-substituted diaminoglyoxime (H2L) containing a diazatetraoxa macrobicycle [2.2.2(B)] has been synthesized from an aromatic primary amine attached to the cryptand moiety and cyanogen-di-N-oxide. The BF2+-capped Co(III) and heterotri-nuclear complexes of the vic-dioxime were prepared. The new compounds were characterized by a combination of elemental analysis and H-1 NMR, C-13 NMR, IR and MS spectral data.