Interactions between the aldehyde and anhydride groups in the diterpenoid fujenal


Hanson J., Hitchcock P., Pibiri I., UYANIK C.

JOURNAL OF CHEMICAL RESEARCH-S, sa.12, ss.647-648, 2002 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Konu: 12
  • Basım Tarihi: 2002
  • Doi Numarası: 10.3184/030823402103171131
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH-S
  • Sayfa Sayıları: ss.647-648

Özet

Methanolysis of the diterpenoid aldehyde:anhydride, fujenal, catalysed by tetracyanoethylene afforded C-6:C-7 methoxylactones whilst the addition of methyl magnesium bromide to fujenal afforded a 6,7-lactone but with an cis A/B ring junction; the structures of these products were established by X-ray crystallography.