Complexation of titanium alkoxides with cis-2-butene-1,4-diol and hydrolysis of their products


Kayan A.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS, vol.13, pp.29-39, 2003 (Journal Indexed in SCI) identifier

  • Publication Type: Article / Article
  • Volume: 13
  • Publication Date: 2003
  • Doi Number: 10.1023/a:1022948830154
  • Title of Journal : JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS
  • Page Numbers: pp.29-39

Abstract

Reaction of Ti(OEt)(4) and Ti(OBun)(4) with cis-2-butene-1,4-diol (B.diol-2H) in 1:1 molar ratio was studied at room temperature using the sol-gel process. C-13{H-1}- and H-1-NMR data showed that all the B.diol-2H completely reacted with both titanium alkoxides. Each of the products was hydrolyzed by water. The new hydrolyzed products were characterized by C-13- and H-1-NMR spectroscopy and Karl-Fischer Titration. Thermogravimetric and differential thermal analyses (TGA-DTA) of the hydrolyzed-products were also studied.