Boosting supercapacitor performance via flower-like Cu2XSnS4 (X = Mn, Co, Ni, Ba, Zn) chalcogenides: Solvothermal synthesis and charge storage behavior

Colak S. G., GÜNGÖR A., Colak M. O. A., Simsek U. B., Genc R., Erdem E.

JOURNAL OF COLLOID AND INTERFACE SCIENCE, cilt.701, 2026 (SCI-Expanded, Scopus) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 701
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1016/j.jcis.2025.138672
  • Dergi Adı: JOURNAL OF COLLOID AND INTERFACE SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Applied Science & Technology Source, CAB Abstracts, Chemical Abstracts Core, Chimica, Compendex, INSPEC, Veterinary Science Database
  • Kocaeli Üniversitesi Adresli: Evet

Özet

In the present work, a series of Cu2XSnS4 (X = Mn, Co, Ni, Zn, Ba) quaternary chalcogenide phases were synthesized by a simple solvothermal method and evaluated as electrode materials in symmetric two-electrode supercapacitor cells. Structural and morphological analyses demonstrated the formation of flower-like crystalline structures, with significant variations in texture and surface area depending on the substituted metal. Among the synthesized samples, the Mn-substituted CMnTS electrode exhibited the highest specific capacitance of 386.0 F/g at a current density of 1.0 A/g and maintained 92 % of its initial capacity after 10,000 charge-discharge cycles. Electrochemical tests revealed that CMnTS stored charge predominantly through capacitive mechanisms, while the Zn-substituted sample exhibited diffusion-limited behavior. EPR analysis indicated the presence of paramagnetic species in CMnTS, which may contribute to its electrochemical performance. These findings highlight the critical role of metal substitution in tailoring the charge storage characteristics of quaternary chalcogenides and provide a promising approach for optimizing electrode materials.