Ethanolysis of steroidal epoxides catalysed by tetracyanoethylene

Uyanik C., Koca O.

JOURNAL OF CHEMICAL RESEARCH, sa.9, ss.525-527, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: Sayı: 9
  • Basım Tarihi: 2010
  • Doi Numarası: 10.3184/030823410x12843965017463
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.525-527
  • Kocaeli Üniversitesi Adresli: Evet

Özet

Ethanolysis of the epimeric androstane 4,5- and 5,6- epoxides catalysed by tetracyanoethylene is reported. In contrast to other reagents, these reactions involve the mild room temperature trans diaxial opening of the epoxides. The stereochemistry of three of the products was established by X-ray crystallography.