A C-13 NMR method for determining the stereochemistry of the A/B ring junction in B-norsteroids

Hanson J., Hitchcock P., Thangavelu V., UYANIK C.

JOURNAL OF CHEMICAL RESEARCH-S, no.1, pp.18-21, 1999 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: Issue: 1
  • Publication Date: 1999
  • Doi Number: 10.1039/a806378h
  • Journal Name: JOURNAL OF CHEMICAL RESEARCH-S
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.18-21
  • Kocaeli University Affiliated: Yes

Abstract

A correlation between the position of the C-13 NMR signal for the C-10 methyl group (C-19) and the stereochemistry of the A/B ring junction has been established and applied to the determination of the stereochemistry of the products of the hydroboration of B-norandrosta-3,5-dien-17-one.