Synthesis and Characterization of <i>N</i>-(2,2-Diphenylacetyl)-<i>N</i>′-Substituted Thiourea Derivatives: The Crystal Structure of <i>N-</i>(2,2-Diphenylacetyl)-<i>N</i>′-(4-chloro phenyl)-thiourea

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Mansuroglu D., Arslan H., VanDerveer D., Binzet G.

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, cilt.184, sa.12, ss.3221-3230, 2009 (SCI-Expanded, Scopus)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 184 Sayı: 12
• Basım Tarihi: 2009
• Doi Numarası: 10.1080/10426500902979743
• Dergi Adı: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.3221-3230
• Kocaeli Üniversitesi Adresli: Evet

Özet

A series of new N-(2,2-diphenylacetyl)-N'-substituted thiourea derivatives (1-9) have been prepared and characterized by elemental analyses, IR and H-1 NMR spectroscopy. N-(2,2-diphenylacetyl)-N'-(4-chlorophenyl)-thiourea was also characterized by a single crystal X-ray diffraction study. The compound crystallizes in the monoclinic space group P2(1)/c with Z = 4 and a = 9.6551(19) angstrom, b = 20.060(4) angstrom, c = 9.894(2) angstrom, beta = 104.29(3)degrees. The molecular conformation of the compound is stabilized by an intramolecular (N1-H1 center dot center dot center dot O1) hydrogen bond that forms a pseudo-six-membered ring.