Synthesis and characterization of new metal-free and metallophthalocyanines containing macrobicyclic moieties


Bilgin A., Gok Y.

SUPRAMOLECULAR CHEMISTRY, cilt.18, sa.6, ss.491-499, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 18 Sayı: 6
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1080/10610270600717672
  • Dergi Adı: SUPRAMOLECULAR CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.491-499
  • Kocaeli Üniversitesi Adresli: Evet

Özet

The metal-free 5,10 and metallophthalocyanines 11-13 ( M = Ni, Zn, Cu) fused in peripheral positions with diazadithiatetraoxa or diazahexaoxamacrobicycles have been prepared by bicyclotetramerization of the newly synthesized isoindolinediimine derivatives of cryptands 4,9 or dicyano substituted macrobicycles 3,8 in the presence of the corresponding metal salts or a strong organic base. The new compounds have been characterized by elemental analysis, H-1 and C-13-NMR, IR, UV-visible and mass spectral data.