Synthesis and characterization of new metal-free and metallophthalocyanines containing macrobicyclic moieties

Bilgin A. , Gok Y.

SUPRAMOLECULAR CHEMISTRY, cilt.18, ss.491-499, 2006 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 18 Konu: 6
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1080/10610270600717672
  • Sayfa Sayıları: ss.491-499


The metal-free 5,10 and metallophthalocyanines 11-13 ( M = Ni, Zn, Cu) fused in peripheral positions with diazadithiatetraoxa or diazahexaoxamacrobicycles have been prepared by bicyclotetramerization of the newly synthesized isoindolinediimine derivatives of cryptands 4,9 or dicyano substituted macrobicycles 3,8 in the presence of the corresponding metal salts or a strong organic base. The new compounds have been characterized by elemental analysis, H-1 and C-13-NMR, IR, UV-visible and mass spectral data.