Synthesis and characterization of new metal-free and metallophthalocyanines containing macrobicyclic moieties


Bilgin A. , Gok Y.

SUPRAMOLECULAR CHEMISTRY, vol.18, no.6, pp.491-499, 2006 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 18 Issue: 6
  • Publication Date: 2006
  • Doi Number: 10.1080/10610270600717672
  • Title of Journal : SUPRAMOLECULAR CHEMISTRY
  • Page Numbers: pp.491-499

Abstract

The metal-free 5,10 and metallophthalocyanines 11-13 ( M = Ni, Zn, Cu) fused in peripheral positions with diazadithiatetraoxa or diazahexaoxamacrobicycles have been prepared by bicyclotetramerization of the newly synthesized isoindolinediimine derivatives of cryptands 4,9 or dicyano substituted macrobicycles 3,8 in the presence of the corresponding metal salts or a strong organic base. The new compounds have been characterized by elemental analysis, H-1 and C-13-NMR, IR, UV-visible and mass spectral data.