The stereochemistry of reactions of 5 beta-androst-3-enes


Hanson J., Hitchcock P., Al-Jayyousi S., UYANIK C.

JOURNAL OF CHEMICAL RESEARCH-S, no.8, pp.420-424, 1998 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: Issue: 8
  • Publication Date: 1998
  • Doi Number: 10.1039/a800578h
  • Title of Journal : JOURNAL OF CHEMICAL RESEARCH-S
  • Page Numbers: pp.420-424

Abstract

Spectroscopic and crystallographic studies shows that the epoxidation, osmylation and bromination of 17 beta-acetoxy-5 beta-androst-3-ene takes place from the beta-face of the alkene and that a diequatorial dibromide and bromohydrin accompany the diaxial addition products.