Dynamic and static fluorescence quenching on the inclusion complex formed by [3-(4-methylphenyl)-4,5-dihydro-1,2-oxazole-4,5-diyl] bis (methylene) diacetate and methyl-beta-cyclodextrin in aqueous media

Ay Ü., Sarli S. E., KARA Y. S.

SPECTROSCOPY LETTERS, vol.53, no.9, pp.692-704, 2020 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 53 Issue: 9
  • Publication Date: 2020
  • Doi Number: 10.1080/00387010.2020.1824194
  • Journal Name: SPECTROSCOPY LETTERS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Analytical Abstracts, Applied Science & Technology Source, Biotechnology Research Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, INSPEC, Metadex, Civil Engineering Abstracts
  • Page Numbers: pp.692-704
  • Keywords: Fluorescence lifetime, inclusion complex, isoxazole derivatives, quenching mechanism, transition metals, DIFFUSION-CONTROLLED REACTIONS, CARBON-TETRACHLORIDE, DERIVATIVES, ANILINE, DESIGN, INHIBITORS, TRANSIENT, COUMARIN, AGENTS
  • Kocaeli University Affiliated: Yes

Abstract

An inclusion complex was formed between [3-(4-methylphenyl)-4,5-dihydro-1,2-oxazole-4,5-diyl] bis (methylene) diacetate compound, an isoxazole derivative and methyl-beta-cyclodextrin, the smallest unit of the macrocyclic family. With this newly formed fluorescent probe, the induced photophysical properties of heavy metals were investigated. The complex was thermally analyzed by differential scanning calorimetry - thermogravimetry, Fourier transform infrared, proton nuclear magnetic resonance and two dimensional correlated spectroscopy techniques were used for spectral characterization. Complex formation constant, Gibbs free energy and approximate quenching activation energy values were calculated. Lifetime, bimolecular quenching rate constant values and diffusion rate constant calculations were made and the mechanism of the quenching event with heavy metal effect was trying to be clarified. Whether quenching with Zn is dynamic, and whether or not quenching with Fe is static and diffusion controlled were investigated by the sphere of action static quenching, and by the finite sink approximation models.